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Abstract Zero‐dimensional (0D) organic metal halide hybrids (OMHHs) are emerging materials with significant potential for optoelectronic applications, including direct X‐ray detectors. While 0D OMHH single crystals exhibit excellent X‐ray detection properties, their scalability remains a significant challenge due to the time‐intensive growth process and difficulty in producing large single crystals exceeding a few centimeters. This limitation hinders their practicality for large‐area detector applications. Here, we report for the first time the development of amorphous 0D OMHH films via solution processing for efficient direct X‐ray detection. By reacting a non‐crystalline organic halide, triphenyl(9‐phenyl‐9H‐carbazol‐3‐yl)phosphonium bromide (TPPCarzBr), with zinc bromide (ZnBr₂), we have successfully produced amorphous 0D (TPPCarz)₂ZnBr₄films with controlled thickness via facile solution processing. The organic cations (TPPCarz⁺) feature a lower bandgap than the ZnBr₄²⁻anions, enabling efficient molecular sensitization, where ZnBr₄²⁻anions serve as X‐ray absorbers and TPPCarz⁺ cations as charge transporters. Direct X‐ray detectors based on 0D (TPPCarz)₂ZnBr₄films demonstrate outstanding performance, achieving a stable X‐ray detection sensitivity of 2,165 µC Gy_air⁻¹cm⁻²at 20 V mm⁻¹ and a detection limit of 6.01 nGy_air s⁻¹. The amorphous nature of these films enhances their processability, allowing for fabrication in various sizes and shapes, and making them highly adaptable for scalable detector applications.